Park Research Group Menu Home Research Yoonsu Team Publications Photos Lab Tour Publications [1] Visible Light-Driven, Iridium-Catalyzed Hydrogen Atom Transfer: Mechanistic Studies, Identification of Intermediates and Catalyst Improvements. Park, Y.†; Tian, L.†; Kim, S.; Pabst, T. P.; Kim, J.; Scholes, G. D.; Chirik, P. J. JACS Au 2022, 2, 407-418 (†Co-first authors). [29] Iridium-Catalyzed Chemo-, Diastereo-, and Enantioselelctive Allyl-Allyl Coupling: Accessing All Four Stereoisomers of (E)-1-Boryl-Substituted 1,5-Dienes by Chirality Pairing. Yongsuk Jung,† Seok Yeol Yoo,† Yonghoon Jin, Jaehyun You,‡ Seungcheol Han, Jeongwoo Yu, Yoonsu Park,* Seung Hwan Cho* Angew. Chem. Int. Ed. 2023, e202218794 (†Co-first authors, ‡Undergraduate). Selected as a Hot Paper. Postdoc Works The Park Laboratory Postdoc Works [28] Pentamethylcyclopentadienyl Metalloradical Iron Complexes Containing Redox Noninnocent α-Diimine-type Ligands: Synthesis, Molecular and Electronic Structures. Park, Y.; Zhong, H.; Pabst, T. P.; Kim, J.; Chirik, P. J. Organometallics 2023, 42, 465-472. [27] Ammonia synthesis by photocatalytic hydrogenation of a N2-derived molybdenum nitride. Kim, S.; Park, Y.; Kim, J.; Pabst, T. P.; Chirik, P. J. Nature Synth. 2022, 1, 297-303. [26] Visible Light-Driven, Iridium-Catalyzed Hydrogen Atom Transfer: Mechanistic Studies, Identification of Intermediates and Catalyst Improvements. Park, Y.†; Tian, L.†; Kim, S.; Pabst, T. P.; Kim, J.; Scholes, G. D.; Chirik, P. J. JACS Au 2022, 2, 407-418 (†Co-first authors). [25] Visible Light Enables Catalytic Formation of Weak Chemical Bonds with Molecular Hydrogen. Park, Y.; Kim, S.; Tian, L.; Zhong, H.; Scholes, G. D.; Chirik, P. J. Nature Chem. 2021, 13, 969-976. Highlighted by Princeton University. [24] Synthesis, Electronic Structure, and Reactivity of a Planar Four-Coordinate, Cobalt-Imido Complex. Park, Y.; Semproni, S. P.; Zhong, H. Chirik, P. J. Angew. Chem. Int. Ed. 2021, 60, 14376-14380. [23] Visible-Light-Enhanced Cobalt-Catalyzed Hydrogenations: Switchable Catalysis Enabled by Divergence between Thermal and Photochemical Pathways Mendelsohn, L. N.; MacNeil, C. S.; Tian, L.; Park, Y.; Scholes, G. D.; Chirik, P. J. ACS Catal. 2021, 11, 1351. [22] The Future of Scientific Leadership is Interdisciplinary: The 2019 CAS Future Leaders Share Their Vision. (Backstory Article) Milić, J.V.; Ehnbom, A.; Garedew, M.; Vincent-Ruz, P.; Schloemer, T.H.; Hodgson, G. K.; Oakley, M.S.; Sasaki, K.; Chander, S.; Lé garé, M.-A.; Callmann, C. E.; Bismillah, A. N.; van Osch, D.J.G.P.; Sanchez, V.; Boase, N.R.B.; Mambwe, D.; Coley, C.W.; Deng, Y.; Betz, K.N.; Sanjosé-Orduna, J.; Natoli, S.; Zhang, L.; Bakulina, O.; Fereyduni, E.; Hilario-Martínez, J.C.; Busta, L.; Hunter, A.; Park, Y.; Zadeh, F. H. iScience 2020, 23, 101442. [21] Catalytic Hydrogenation of a Manganese(V) Nitride to Ammonia. Kim, S.; Zhong, H.; Park, Y.; Loose, F.; Chirik, P. J. J. Am. Chem. Soc. 2020, 142, 9518–9524. Graduate and Undergraduate Works The Park Laboratory Graduate and Undergraduate Works [20] Harnessing Secondary Coordination Sphere Interactions that Enable the Selective Amidation of Benzylic C−H Bonds. Jung, H.; Schrader, M.; Kim, D.; Baik, M.-H.*; Park, Y.*; Chang, S.* J. Am. Chem. Soc. 2019, 141, 15356–15366. (*Co-corresponding authors). [19] Asymmetric Formation of of γ-Lactams via C–H Amidation Enabled by Chiral Hydrogen-Bond-Donor Catalysts Park, Y. & Chang, S. Nature Catal. 2019, 2, 219.Highlighted in News & Views of Nature Catalysis. 2020년 대한민국 국가연구개발 우수성과 100선 선정. PDF [18] Iridium-Catalyzed Enantioselective C(sp3)–H Amidation Controlled by Attractive Noncovalent Interactions. Wang, H.; Park, Y.; Bai, Z.; Chang, S.; He, G.; Chen, G. J. Am. Chem. Soc. 2019,141, 7194–7201. [17] Ni-Mediated Generation of "CN" Unit from Formamide and Its Catalysis in the Cyanation Reactions. Yang, L.; Liu, Y.-T.; Park, Y.; Park, S.-W., Chang, S. ACS Catal. 2019, 9, 3360–3365. [16] Revisiting Arene C(sp2)–H Amidation via Intramolecular Transfer of Iridium Nitrenoids: Evidence for a Spirocyclization Pathway. Hwang, Y.†; Park, Y.†; Kim, Y.B.; Kim, D.; Chang, S.Angew. Chem. Int. Ed. 2018, 57, 13565–13569 (†Co-first authors). [15] Selective Formation of γ-Lactams via C–H Amidation Enabled by Tailored Iridium Catalysts. Hong, S. Y.†; Park, Y.†; Hwang, Y.; Kim, Y.; Baik, M.-H.; Chang, S. Science 2018, 359, 1016–1021 (†Co-first authors). Highlighted in Nature, Synfacts, Organic Chemistry Portal, and Science Daily. [14] Delineating Physical Organic Parameters in Site-Selective C–H Functionalization of Indoles. Kim, Y.†; Park, Y.†; Chang, S. ACS Cent. Sci. 2018, 4, 768–775 (†Co-first authors). [13] Quantifying Structural Effects of Amino Acid Ligands in Pd(II)-Catalyzed Enantioselective C–H Functionalization Reactions Park, Y.; Niemeyer, Z. L.; Yu, J.-Q.; Sigman, M. S. Organometallics 2018, 37, 203–210.Featured as a Cover Art in Volume 37, Issue 2. Cover Art [12] Iridium-Catalysed Arylation of C–H Bonds Enabled by Oxidatively Induced Reductive Elimination. Shin, K.; Park, Y.; Baik, M.-H.; Chang, S. Nat. Chem. 2018, 10, 218–224. [11] Transition Metal-Catalyzed C–H Amination: Scope, Mechanism & Applications. (Review Article) Park, Y.; Kim, Y.; Chang, S. Chem. Rev. 2017, 117, 9247–9301.Special issue for C-H activation. [10] Mechanism-Driven Approach to Develop a Mild and Versatile C–H Amidation through Ir(III) Catalysis. Hwang, Y.†; Park, Y.†; Chang, S. Chem. Eur. J. 2017, 23, 11147–11152 (†Co-first author). [9] Why is the Ir(III)-Mediated Amido Transfer So Much Faster than the Rh(III)-Mediated Reaction? A Combined Experimental and Computational Study. Park, Y.; Heo, J.; Baik, M.-H.; Chang, S. J. Am. Chem. Soc. 2016, 138, 14020–14029. [8] The Mechanism of Rh-Catalyzed Oxidative Cyclizations: Closed vs. Open Shell Pathways. Park, Y.; Ahn, S.; Kang, D.; Baik, M.-H. Acc. Chem. Res. 2016, 49, 1263–1270. [7] Study of Sustainability and Scalability in the Cp*Rh(III)-Catalyzed Direct C–H Amidation with 1,4,2-Dioxazol-5-ones. Park, Y.; Jee, S.; Kim, J. G.; Chang, S. Org. Process Res. Dev. 2015, 19, 1024–1029.Selected as ACS Editors’ Choice. [6] Mechanistic Studies on the Rh(III)-Mediated Amido Transfer Process Leading to Robust C–H Amination with a New Type of Amidating Reagent. Park, Y.; Park, K. T.; Kim, J. G.; Chang, S. J. Am. Chem. Soc. 2015, 137, 4534–4542. [5] Rh(III)-Catalyzed Traceless Coupling of Quinoline N-Oxides with Internal Diarylalkynes. Sharma, U.; Park, Y.; Chang, S. J. Org. Chem. 2014, 79, 9899–9906. [4] Mechanistic Studies of the Rhodium-Catalyzed Direct C–H Amination Reaction Using Azides as the Nitrogen Source Park, S. H.; Kwak, J.; Shin, K. Ryu, J.; Park, Y.; Chang, S. J. Am. Chem. Soc. 2014, 136, 2492–2502. [3] Regiodivergent Access to Five- and Six-Membered Benzo-Fused Lactams: Ru-Catalyzed Olefin Hydrocarbamoylation. Li, B.; Park, Y.; Chang, S. J. Am. Chem. Soc. 2014, 136, 1125–1131. [2] Rhodium-Catalyzed Direct Amination of Arene C–H Bonds Using Azides as the Nitrogen Source. Park, S. H.; Park, Y.; Chang, S. Org. Synth. 2014, 91, 52–59. [1] Discovery of New Benzothiazole-Based Inhibitors of Breakpoint Cluster Region-Abelson Kinase Including the T315I Mutant. Hong S.; Kim J.; Yun, S.-M.; Lee, H.; Park, Y.; Hong, S.-S.; Hong, S. J. Med. Chem. 2013, 56, 3531–3545. Home Research Yoonsu Team Publications Photos © The Park Laboratory, 2023.Address: Rm. 604, E6-6, KAIST, 291 Daehak-ro, Yuseong-gu, Daejeon 34141, Republic of Korea © The Park Laboratory, 2023. Address: Rm. 604, E6-6, KAIST, 291 Daehak-ro, Yuseong-gu, Daejeon 34141, Republic of Korea